Characterization of the fracture surface was made using sem and sem eds. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. The intergranular penetrations are attributed to general corrosive attack rather than stress corrosion cracking scc. Investigation of stress corrosion cracking of austenitic. In the past, hydrostatic testing has been frequently used to assess and mitigate stress corrosion cracking. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. The fractured brass tee fitting was subjected to chemical analysis to verify the chemical composition. Stress corrosion cracking international institute of. Stress corrosion cracking can be either intergranular along the grain boundaries, figure 1, or transgranular across the grains, figure 2. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Highpurity copper is immune to stress corrosion cracking in most.
What causes stress corrosion cracking in pipelines. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory tests in seawater and in many organic liquids containing traces of water. Transgranular stress corrosion cracking tgscc is a typical fracture mode for the scc system of stainless steels in chloride environments, characterized by riverlike fractographs 15. Stress corrosion cracking can be either intergranular along the grain boundaries, figure 1, or transgranular across the grains, figure 2, or both, depending on the conditions. The brittle fracture of the material without any visible corrosion products is a feature of stress corrosion cracking. A large, elongated alpha plus beta grain structure was noted. The sensitized 254 smo showed a significative cracking transgranular. Thosearelayer corrosion, intergranular corrosion cracking, and stress corrosion cracking. Stress corrosion cracking of carbon steel in ethanol. The investigation included visual examination, optical microscopy, scanning electron microscopy sem, energy dispersive spectroscopy eds, spectrometry, and metallography. Transgranular stress corrosion cracking tscc in disordered copper25 at.
Stress corrosion cracking scc may be defined as the delayed failure of alloys by. Modeling of inter and transgranular stress corrosion. Mechanisms of transgranular stress corrosion cracking of. Branched, brittle cracks were observed in the failure region and exhibited transgranular propagation. The crack morphology, branching, and multiple fingers, indicate stress corrosion cracking. The type of cracking observed was a function of the degree to which the specimens were sensitized. Mechanistic differences in transgranular and intergranular. The mechanism of transgranular stress corrosion cracking tgscc of noble metal alloys that. The presence of stress leads to failure of this passive film by plastic strain and active corrosion occurs by. Otherwise, through a scanning electron microscope sem fractograph, the. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc.
Stress corrosion cracking in welded 316ss screener shaft. Stresscorrosioncracking view from the penthouse the. Testing the filminduced cleavage model of stress corrosion cracking. A transgranular fracture is a fracture that follows the pattern of grains in the individual lattices of the material. Susceptibility to stress corrosion cracking of 254smo ss. Fractured brass tee fitting metallurgical technologies, inc. Transgranular, granulated, and intergranular stress. Transgranular stress corrosion cracking of 304l stainless. Cracking of stainless steel nozzle sleeve metallurgical. Both intergranular and transgranular stress corrosion cracking is simulated in an efficient manner. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack.
Intergranular stress corrosion cracking scc of pipelines has been known to. An additional document titled addendum on circumferential scc was published in 1998 that specifically addressed the much lesscommon circumferential scc. Lowenergy edxa novel approach to study stress corrosion. Secondary intergranular and transgranular cracking is observed only on scc fracture surfaces and ligament morphology can be different in scc relative to fc. Microscopy study of intergranular stress corrosion. Stress corrosion cracking scc is the formation and growth of crack. The stress corrosion cracking in expanded parts of stainless steel heat exchangers and its prevention were studied. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. When there is no stress, the metal is not reactive to the environment because of the existing of a protective passive film at the crack tip. When alloyed with oxygen or aluminum, transgranular stress corrosion cracking can be induced in laboratory tests in seawater and in many organic liquids containing traces of water. Austenitic stainless steels, transgranular stress corrosion susceptibility of which may be due to nucleation of a phase at stacking faults, or to formation of passive surface films, or to a combination of both effects.
Intergranular fracture an overview sciencedirect topics. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. The fatigue fracture is brittle and the cracks are most often transgranular, as in stress corrosion cracking, but not branched. Kainer, evaluation of the delayed hydride cracking mechanism for transgranular stress corrosion cracking of magnesium alloys, materials science and engineering. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Some of the shallow intergranular penetrations were driven to significant depths due to corrosion fatigue. Feb 06, 2011 sem micrograph mechanisms of scc there are 3 possible mechanisms. This is known as cscc or chloride stress corrosion cracking. Lippold j and alexandrov b, phase transformations during welding and postweld heat treatment of a 12cr6.
Transgranular attack has a very characteristic branching habit which is easily recognizable in scanning electron microscopy sem fractographic and metallographic section examination. Atrens, metallurgical aspects of rock bolt stress corrosion. However, very few service failures have been observed. Analysis of fracture surfaces using scanning electron microscopy. Commercial titanium can suffer intergranular stresscorrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. Although intergranular stress corrosion cracking igscc of highpressure gas pipelines has been known for more than 20 years, a transgranular form tgscc was detected more recently.
It is concluded that stress corrosion cracking was the main reason for the cracking of the elbow. Characterization of intergranular stress corrosion cracking. Stress corrosion cracking of an austenitic stainless steel in. Scc occurs as a result of a combination between corrosion and tensile stress. Transgranular stress corrosion cracking tgscc was identified for plain specimens machined from ascast pure mg and az91 ingots and subjected to linearly increasing stress in 5 gl nacl solutions. For a prevention of future failure, it is necessary to elucidate the corrosion type in damaged components. Analytical results revealed that crack was propagated at the outer surface of the welded zone. The importance of a conjoint action of corrosion and stress as well as the nature of. Fracture mechanicsbased testing was used to quantify the stress corrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in.
The picture shown here reveals a primary corrosion fatigue crack that in part has been widened by a secondary corrosion reaction. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 1115 march 2007. Oct 24, 20 a transgranular fracture is a fracture that follows the pattern of grains in the individual lattices of the material. Stress corrosion cracking scc of the highperformance rareearth containing magnesium alloys ze41, qe22 and elektron 21 ev31a was studied using slow strain rate test ssrt method in air, distilled water and 0. Potentiostatic polarization, constant deflection tests, and highresolution sem examination. Transgranular stresscorrosion cracking of disordered cu.
This is a 304l stainless steel and was caused from chloride. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Stress corrosion cracking of stainless steel components in. Sem fractograph of intergranular scc of type 316 stainless steel in polythionic acid showing brittle features. Results indicate the brass plumbing fitting fractured due to stress corrosion cracking scc. Liquid metal cracking lmc, usually a physicochemical process. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. Corrosion is related to the susceptibility of the material to the environment, while stresses may be residual, external or. Characterization of intergranular stress corrosion. Stress corrosion cracking of an austenitic stainless steel.
Stress corrosion cracking of cuzn and cua1 alloys in cuprous ammonia solutions can only occur when the parting limits for dealloying are exceeded. The crack initiated on the id surface of the brass tee fitting in the area where an outer diameter od compression ring is crimped to secure tubing to the brass fitting. Scc experiments that transgranular cracking of annealed aisi 304 stainless steel. Pdf stress corrosion cracking damages researchgate. The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steelelectrolyte interface, which are formed by the applied cathodic current to protect the structure 71. Cl and s elements were detected in corrosion products from the corrosion pits and the cracks by eds. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i. Mechanisms of stresscorrosion cracking asm international. Potentiodynamic polarization curves measured in the above environment were identical for both the solution annealed and sensitized conditions, but the latter showed slightly greater current densities cds.
Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Transgranular stresscorrosion cracking tscc in disordered copper25 at. Current fluctuations have been measured during potentiostatic transgranular stress corrosion cracking scc of copper, alpha brass and type 304 stainless steel. It failed by stress corrosion cracking, which was originated at the welded zone. A study was made to investigate the transgranular fracture mechanism of zirconium in an iodine environment using the data from stress corrosion cracking scc tests of ir radiated zirconiumlined tubes and the analyses of the force on dislocations in zirconium liner during sec testing. Transgranular stresscorrosion cracking of disordered cu25au. Stress corrosion cracking of a forged mgalzn alloy with different surface conditions. Stress corrosion cracking scc is a type of environmentallyassisted cracking eac, or the formation of cracks caused by various factors combined with the environment surrounding the pipeline. Stress corrosion cracking scc is an important failure mechanism for oil and gas pipelines. Transgranular stress corrosion cracking, tgscc, is observed in alloys with 20 or 30% zn but not in alloys with 0. Stress corrosion cracking of carbon steel in ethanolgasoline.
Application of the surfacemobility stress corrosion cracking mechanism to nuclear materials. The abilities of the proposed model are illustrated through several numerical examples involving a full prediction of complex crack network growth induced by stress corrosion cracking within 2d polycrystaline models. Chloride is the leading cause of transgranular cracking. Based on the temperature, available moisture, stress level, and type of material used it was determined that the likely cause of failure was neutral ph, dilute chlorideinduced stress corrosion cracking. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Semeds analysis of corrosion products from the interior of a. Effect of solution treatment on stress corrosion cracking. Transgranular fractures are also known as transcrystalline fractures. Both intergranular and transgranular stress corrosion cracking are observed. Intergranular stress corrosion cracking igscc in type sus304. A limited number of tests were also performed on polycrystals in the chloride media and also in acidified 1 m na2so4.
Intergranular stress corrosion cracking an overview. Sem eds analysis of corrosion products from the interior. Scanning electron microscopy sem showed that a transition from igscc to transgranular stress corrosion cracking tgscc occurred at greater nitrogen contents. Intergranular cracking is a form of corrosive attack that progresses preferentially along grain boundaries. Woollin p, postweld heat treatment to avoid intergranular stress corrosion cracking of supermartensitic stainless steels, proc conf stainless steel world 2005, kci publishing, paper no.
Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. The degree of sensitization also determined the tensile properties observed in the specimens after these slow strain rate tensile tests. Instances of tgscc have been associated with dilute solutions with ph values in the region of 6. Transgranular, intergranular, and granulated stress corrosion cracks were observed. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel. Intergranular stress corrosion cracking of welded steel twi. Fractography and surface observation indicated that the stress corrosion cracking mode for asforged samples was dominated by transgranular and partially intergranular morphology, whereas the. Microscopy study of intergranular stress corrosion cracking. Liquid and solid metal embrittlement has also been reported. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Sem observation of the fracture surface of solubilized and sensitized 254smo, in 3 moll sodium chloride at ph 1, showed that in solubilized conditions the fracture was essentially ductile and only a very narrow zone presented transgranular crack. Transgranular stress corrosion cracking occurs mainly in chloride cracking of austenitic steels.
Model test blocks of the exchangers were constructed with tubes expanded by. Temperature is a significant environmental factor affecting cracking. The effects of thermomechanical processing on the stress corrosion cracking resistance of sensitised type 304 austenitic stainless steel has therefore been studied 35, based on the proposition that resistance to stress corrosion cracking develops from crack bridging, which is a consequence of grain boundary triple. Stress corrosion crack initiation and propagation in longitudinally. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Other problems that have been observed with inconel include wastage, tube denting, pitting, and intergranular attack. Periodic current transients with very short rise times have been shown to be simultaneous with acoustic events. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Transgranular article about transgranular by the free.
Stress corrosion cracking of a 304 stainless steel elbow. In the scanning electron microscope, intergranular stresscorrosion cracks have the classic rock candy appearance, with little if any evidence of. Transgranular stress corrosion cracking an overview. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Occasionally, both types of cracking are observed in a failure. Cepa stress corrosion cracking recommended practices 2nd edition. Intergranular stress corrosion cracking of copper a case study. It has been reported that the environmentalfracture is discontinuous at the micron scale 4.
The stress corrosion cracking scc behavior of x65 carbon steel was investigated in simulated fuelgrade ethanol sfge using the slow strain rate test method, potentiodynamic polarization. Circumferential corrosion fatigue cracking was mainly driven by thermal stress cycles and corrosion. Stress corrosion cracking of carbon steel in aerated ethanolgasoline blend was studied using notched slow strain rate testing. The interaction of corrosion fatigue and stresscorrosion. Transgranular fracture mechanism of zirconium in iodine.
Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature. Kainer, comparison of the linearly increasing stress test and the constant extension rate test in the evaluation of transgranular stress corrosion cracking of magnesium, mater. Optical microscopy and sem observations show that the cracks propagate along. Film breakdown and anodic dissolution during stress. Transgranular liquation cracking of grains in the semisolid state. Stress corrosion cracking, corrosionfatigue, fractography, boric acid, chloride, tem, sem, dislocation, crack arrest marking, oxide scale. Stresscorrosioncracking view from the penthouse the dnfm. Intergranular stress corrosion cracking scc was produced in ethanolgasoline blend with 15. Current fluctuations have been measured during potentiostatic transgranular stresscorrosion cracking scc of copper, alpha brass and type 304 stainless steel. Intergranular stress corrosion cracking igscc is more common than transgranular scc. The effect of nitrogen on stress corrosion cracking of. Those pictures show that the weld nugget is sensitive to pitting corrosion when it is not submitted to a mechanical loading gure 3a.
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